Page 118 - CatalogNEP-PS

PRACTICAL (30 Hours)

1. Qualitative Analysis: Separation, purification, and identification of binary mixture of
organic compounds by chemical tests.
2. Organic Synthesis:
29. Acetylation: - Acetylation of cholesterol and separation of cholesteryl acetate by column
chromatography.
30. Oxidation: Adipic acid by chromic acid oxidation of cyclohexanol.
31. Grignard reaction: Synthesis of triphenyl methanol from benzoic acid.
32. Aldol condensation: Dibenzal acetone from benzaldehyde.

SUGGUESTED READINGS:

1. Finar l. L, Organic Chemistry, Vol.1, 2, Pubs: ELBS (1994).
2. Nicolaou K.C. and Sorensen E.J., Classics in Total Synthesis, Pubs: VCHN.Y.(1986).
3. Nicolaou K.C. and Synder, S.A.Classics in Total Synthesis II, Pubs: VCH N.Y.(2003).
4. Akhrem, A.A.Total Steroids Synthesis, Pubs: Plenum Press, New York, (1970)
5. Solomon T.W.G. and Fryhle C.B., Organic Chemistry, 7thEdn., Pubs: John. Wiley & Sons
Inc. N.Y. (2000).
6. Manitto P., Biosynthesis of Natural Products, Pubs: Horwood Ltd.(1981).
7. Padwa, A. Org. Lett. 2007, 9(2), 279-282
8. Macroscale and Microscale Organic Experiments, K.L. Williamson, D.C.Heath.
9. Systematic Qualitative Organic Analysis, H.Middleton, Adward Arnold.
10. Handbook of Organic Analysis-Qualitative and Quantitative, H.Clark, Adward Arnold.
11. Vogel‘s Textbook of Practical Organic Chemistry, A.R. Tatchell, John Wiley.
12. Experiments and Techniques in Organic Chemistry, D.Pasto, C. Johnson and M.Miller,
Prentice Hall.

Chem.413 Statistical Thermodynamics and Quantum Chemistry 3+1

LEARNING OBJECTIVES:

Objectives of this course are:
 to teach the fundamental concepts of statistical thermodynamics and quantum chemistry.
 to provide basic knowledge about applications of quantum chemistry

LEARNING OUTCOMES:

The student will be able to
 to understand the concepts of quantum chemistry
 to apply knowledge gained through the course to fundamental structure of atoms and
molecules.

THEORY (45 Hours)

UNIT-I (11 Hours)

Statistical Thermodynamics:Basic Terminology: probability, phase space, micro and macro
states, thermodynamic probability, statistical weight,
assembly, ensemble, The most probable distribution: Maxwell-Boltzmann distribution, quantum
statistics: The Bose-Einstein statistics and Fermi- Dirac Statistics. Thermodynamic probability
(W) for the three types of statistics. Lagrange‘s undetermined multipliers. Stirling‘s
approximation, Molecular partition function and its importance.

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