Page 121 - CatalogNEP-PS

PRACTICAL (30 Hours)

1. Analysis of mixtures by gravimetric and volumetric methods from the mixture
solutions:
Copper- Nickel
Copper -Magnesium
Copper-Zinc
Iron-Magnesium
Silver-Zinc
Copper-Nickel-Zinc
Fe(II)-Fe(III)
2. Green methods of Preparation of the following:
Bis(acetylacetonato)copper(II)
Tris(acetylacetonato)iron(III)
Tris(acetylacetonato)manganese(III)

SUGGUESTED READINGS:

1. Purcell K.F. and Kotz J.C., Inorganic Chemistry, Pubs: W.B. Saunders & Co., London
(1977).
2. Jolly W.L., Modern Inorganic Chemistry, Pubs: W.B. Saunders & Co., London (1984).
3. Cotton F.A. and Wilkinson G, Advanced Inorganic Chemistry, 5 th Edition, Pubs:Willey
Eastern (1989).
4. Hughes M.N., Inorganic Chemistry of Biological Processes, Pubs: Willey (1972).
5. Dennis, Brown G., Chemistry of Vitamin B-12 and Related Inorganic Model, Systems,
Progress in Inorganic Chemistry (Vol.18)

Chem.422 Pericyclic and Asymmetric Synthesis 3+1

LEARNING OBJECTIVES:

Objectives of this course are:
 to make students familiar about the concepts and applications of pericyclic reactions and
asymmetric organic synthesis.
 to give information about the basic principle of enantioselective reactions and
enantiomeric excess determination.

LEARNING OUTCOMES:

The student will be able to
 To apply the information about the synthetic applications of asymmetric organic
synthesis
 To understand the mechanisms of various pericyclic reactions.

THEORY (45 Hours)

UNIT-I: Pericyclic Reactions-I (11 Hours)

Classification of pericyclic reactions, Molecular orbital and their symmetry properties, molecular
orbitals of ethylene, 1,3-butadiene;1,3,5-hexatriene; allyl system, Woodward-Hoffmann‘s
conservation of orbital symmetry rule; Analysis of pericyclic reactions: FMO approach,
correlation diagrams method and Perturbation of molecular orbital approach. Cycloaddition
reactions: Supra and antra facial additions, 4n and 4n+2 systems, 2+2 additions of ketenes. Diels-
Alder reactions, 1,3-Dipolar cycloaddition and cheletropic reactions, ene reaction, retro-Diels-

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