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a. sugar
b. ethanol
c. sodium chloride
iii. Surface tension of pure solvents, analysis of mixtures of two miscible solvents,
verification of Gibb‘s Thomson Rule of surface tension.
2. Partition – Coefficient: Determination of partition – coefficient for I2 and benzoic acid
between two immiscible solvents.
3. Adsorption Measurements: Verification of Freundlich adsorption isotherm for I2, and
acetic acid on charcoal.
4. Colloidal Solution: Preparation of sol solution of arsenic sulphide and estimation of
flocculation value for NaCl, KCl, BaCl 2, AlCl 3.
SUGGUESTED READINGS:

1. Young R.J. and Lovell P.A., Introduction to Polymers, Pubs: Chapman and Hall, London, 2nd
ed., New Delhi (2004).
rd
2. Billmeyer F.W. Jr., Text book of polymers science, Pubs: Wiley-Interscience, 3 edn.,(1984).
3. Myers D., Surfactant Science and Technology, Pubs: VCH Publishers (1988).
4. Flory P.J., Principles of polymer chemistry, Pubs: Cornell Univ. Press, (Indian Print 2006).
5. Tager A, Physical Chemistry of polymer, Pubs: Mir Publishers, Moscow (1971).
6. Hunter 3. R.J., Foundations of Colloid Science, Vols. I & II, Pubs: Oxford Science
Publications (1989).
7. Rosen M.J., Surfactants and Interfacial Phenomena, Pubs: John Wiley & Sons (1989).

HIGHER & APPLIED AREA LEVEL COURSES:

Chem.414 Advanced Organometallics (3+1)

LEARNING OBJECTIVES:

Objectives of this course are:
 to provide knowledge about the bonding and fluxionality in organometallic compounds of
transition elements.
 to explain homogeneous transition metal catalysis
 to give information about metal-metal bonding in metal clusters.

LEARNING OUTCOMES:

The student will be able to
 get information about different aspects the metal-carbon multiple bonded organometallic
compounds and their different applications
 apply knowledge of homogeneous transition metal catalysis to explain hydrogenation of
organic compounds.
 Explain important homogeneous catalytic reactions and their utility in organic synthesis.

THEORY (45 Hours)

UNIT-I (12 Hours)
Organometallic Compounds of transition elements: Types of ligands and their classifications
in organometallic compounds, 16 and 18 electron rule and its limitations. Hapto-nomenclature,

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