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UNIT-III: Chemistry of p-Block Elements (9 Hours)

Electronic configuration, atomic and ionic size, metallic/non-metallic character, melting point,
ionization enthalpy, electron gain enthalpy, electronegativity, Catenation, Allotropy of C, P, S;
inert pair effect, diagonal relationship between B and Si and anomalous behaviour of first member
of each group.

UNIT – IV: Compounds of p-Block Elements (15 Hours)
Acidic/basic nature, stability, ionic/covalent nature, oxidation/reduction, hydrolysis, action of heat
on the following:Hydrides of Group 13 (only diborane), Group 14, Group 15 (EH3 where E = N,
P,As, Sb, Bi), Group 16 and Group 17, Oxoacids of phosphorus, sulphur and chlorine,
Interhalogen and pseudohalogen compound, Clathrate compounds of noble gases, xenon fluorides
(MO treatment of XeF2).

PRACTICAL (30 Hours)

1. Redox Titrations
(i) Estimation of Fe(II) with K 2Cr 2O 7 using diphenylamine as internal indicator.
(ii) Estimation of Fe(II) with K 2Cr 2O 7 using N-phenyl anthranilic acid as internal indicator.
(iii) Estimation of Fe(II) with K 2Cr 2O 7 using external indicator.
2. Iodo/Iodimetric Titrations
(i) Estimation of Cu(II) using sodium thiosulphate solution.
(ii) Estimation of K 2Cr 2O 7using sodium thiosulphate solution
(iii) Estimation of antimony in tartaremetic iodimetrically.
(iv) Estimation of Iodine content in iodized salt.

SUGGUESTED READINGS:

THEORY
1. Lee, J. D.; (2010), Concise Inorganic Chemistry, Wiley India.
2. Huheey, J. E.; Keiter, E. A.; Keiter; R.L.; Medhi, O.K. (2009), Inorganic Chemistry-
Principles of Structure and Reactivity, Pearson Education.
3. Atkins, P. W.; Overton, T. L.; Rourke, J. P.; Weller, M. T.; Armstrong, F. A. (2010),
Shriver and Atkins Inorganic Chemistry, 5th Edition, Oxford University Press.
4. Miessler, G. L.; Fischer P. J.; Tarr, D. A. (2014), Inorganic Chemistry, 5th Edition,
Pearson.
5. Housecraft, C. E.; Sharpe, A. G., (2018), Inorganic Chemistry, 5thEdition, Pearson.
6. Canham, G. R., Overton, T. (2014), Descriptive Inorganic Chemistry, 6th Edition,
Freeman and Company.
7. Greenwood, N. N.; Earnsaw, A., (1997), Chemistry of Elements, 2nd Edition, Elsevier.
PRACTICAL
1. Jeffery, G. H.; Bassett, J.; Mendham, J.; Denney, R. C. (1989), Vogel‘s Text book of
Quantitative Chemical Analysis, John Wiley and Sons.
2. Harris, D. C.; Lucy, C. A. (2016), Quantitative Chemical Analysis, 9th Edition, Freeman
and Company.
3. Day, R. A.; Underwood, A. L. (2012), Quantitative Analysis, 6th Edition, PHI Learning
Private Limited.

Chem.311 Chemistry of Functional Groups 3+1

LEARNING OBJECTIVES:

The objectives of this course are as follows:

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